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Molecular Conformation and Organic Photochemistry: Time-Resolved Photoionization Studies

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Product Code: 9783642293801
ISBN13: 9783642293801
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$118.37

Molecular Conformation and Organic Photochemistry: Time-Resolved Photoionization Studies

$118.37
 
Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation.
Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.


Author: Rasmus Y. Brogaard
Publisher: Springer
Publication Date: May 18, 2012
Number of Pages: 124 pages
Binding: Hardback or Cased Book
ISBN-10: 3642293808
ISBN-13: 9783642293801
 

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